Ion Size Dependences of the Salting-Out Effect: Reversed Order of Sodium and Lithium Ions
نویسندگان
چکیده
A general trend of the salting-out effect on hydrophobic solutes in aqueous solution is that smaller size a dissolved ion, larger reducing solubility hydrophobe. An exception Li+, smallest alkali metal ions, has notably weaker than Na+. To understand reversed order cation series, we performed molecular dynamics simulations solutions salt ions and calculated Setschenow coefficient methane with ionic radius either or an anion varied wide range. It confirmed correlated packing fraction solution, as observed earlier studies, also partial molar volume ion. Analyses correlation function integrals, fractions solvation spheres, orientations water molecules surrounding ion reveal key differences microscopic properties between which give rise to series volumes ultimately coefficients.
منابع مشابه
fabrication of new ion sensitive field effect transistors (isfet) based on modification of junction-fet for analysis of hydronium, potassium and hydrazinium ions
a novel and ultra low cost isfet electrode and measurement system was designed for isfet application and detection of hydronium, hydrazinium and potassium ions. also, a measuring setup containing appropriate circuits, suitable analyzer (advantech board), de noise reduction elements, cooling system and pc was used for controlling the isfet electrode and various characteristic measurements. the t...
the effect of explicit teaching of metacognitive vocabulary learning strategies on recall and retention of idioms
چکیده ندارد.
15 صفحه اولthe evaluation of language related engagment and task related engagment with the purpose of investigating the effect of metatalk and task typology
abstract while task-based instruction is considered as the most effective way to learn a language in the related literature, it is oversimplified on various grounds. different variables may affect how students are engaged with not only the language but also with the task itself. the present study was conducted to investigate language and task related engagement on the basis of the task typolog...
15 صفحه اولthe effect of task complexity on lexical complexity and grammatical accuracy of efl learners’ argumentative writing
بر اساس فرضیه شناخت رابینسون (2001 و 2003 و 2005) و مدل ظرفیت توجه محدود اسکهان (1998)، این تحقیق تاثیر پیچیدگی تکلیف را بر پیچیدگی واژگان و صحت گرامری نوشتار مباحثه ای 60 نفر از دانشجویان زبان انگلیسی بررسی کرد. میزان پیچیدگی تکلیف از طریق فاکتورهای پراکندگی-منابع تعیین شد. همه ی شرکت کنندگان به صورت نیمه تصادفی به یکی از سه گروه: (1) گروه موضوع، (2) گروه موضوع + اندیشه و (3) گروه موضوع + اندی...
15 صفحه اولذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Journal of Physical Chemistry B
سال: 2021
ISSN: ['1520-6106', '1520-5207']
DOI: https://doi.org/10.1021/acs.jpcb.1c03388